Japan Synchrotron Radiation Research Institute

An additional water is introduced into the manganese cluster during the formation of the S3 state of photosystem II

During photosynthetic water oxidation, the Mn4Ca cluster in Photosystem II progresses through five intermediate Si (i = 0–4) states. X-ray crystallography studies have reported the insertion of one new O ligand during the formation of the S3 state, but recent studies question the...

Time-Temperature-Transformation Diagrams to Navigate the Nucleation and Quenchability of Metastable α-Li₃PS4

α-Li₃PS₄ is a promising solid-state electrolyte with the highest ionic conductivity among its polymorphs. However, its formation presents a thermodynamic paradox: the α-phase is the equilibrium phase at high temperature and transforms to the stable γ-Li3PS4 polymorph when cooled...

Three-Dimensional Real Contact Area at the Tire–Asphalt Interface Revealed by Synchrotron X-Ray CT

Abstract Tire and road wear particles are considered a major source of microplastic pollution globally, necessitating a deeper understanding of friction and wear mechanisms at the tire–road interface. A key parameter governing these phenomena is the real contact area; however, to...

Type-II Charge-Transfer Photogating in a DDCI-4/MoS2 Heterojunction Phototransistor

Abstract Molecular sensitization of two-dimensional semiconductors offers a route to enhanced photodetection, yet the interfacial charge-transfer mechanisms that govern gain in these hybrid devices are often inferred rather than directly established. Here, we report a multilayer...

Advanced Multimodal X-ray Visualization Techniques for Unraveling Catalytic Performance and Degradation Mechanisms of Metal Nanoparticles in Fuel Cells

Abstract This Account highlights the transformative advances enabled by the world-first BL36XU beamline dedicated to in situ and operando characterization of metal nanoparticles and adsorbed species in polymer electrolyte fuel cells (PEFCs). While PEFCs hold great promise for sus...

Pressure-SelectiveMagnetic Switching via SpatiallySeparated Soft Interlayer and Rigid Charge-Transfer Intralayer

Abstract We report a pressure-responsive molecule-based magnet featuring a layered cyanido-bridged Co–W assembly, [{CoII(4-phenoxypyridine)4}3{WV(CN)8}2], exhibiting a distinct pressure-selective magnetic behavior. The compound forms two-dimensional charge-transfer layers with la...

Humidity‐Guided In Situ Polymerization for Controlled Formation of Smooth, Oriented Covalent Organic Framework Films

Efficient, reliable preparation of high-quality films of covalent organic frameworks (COFs) is essential for fully exploring the potential of this class of porous crystalline compounds in, for example, sensing and catalysis. To this end, in situ polymerization on substrates offer...