Materials & Energypreprint2026-08-05

PHOTOELECTRIC EFFECT IN THE TVM FRAMEWORK

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Abstract

ABSTRACT In standard physics, the photoelectric effect is explained by Einstein's equation: where is the work function – an empirical constant characteristic of each metal. This was revolutionary in 1905 because it demonstrated the particle nature of light. However, the work function remains an empirical parameter – its origin is not explained. In the TVM framework, the photoelectric effect is evidence of the quantum nature of light, but TVM additionally explains that its quantum description is a consequence of the geometric structure of metals – the work function and cutoff wavelength are derived from the geometry of the ionization zone, not taken as empirical constants. Starting from: The structure of the metal – a regular crystal lattice with atoms at specific distances The last bound level – the highest occupied energy level (Fermi level) The ionization zone – the space between the last levels of adjacent atoms the paper derives the work function as: where is the width of the ionization zone – the space between the electron clouds of adjacent atoms. By applying the stationarity condition to the electron in the ionization zone, a direct connection is obtained between the work function and the geometry of the crystal lattice. The paper also derives the geometric wavelength of the electron in the zone , as well as the cutoff wavelength of the incident photon , connecting the wave nature of the electron and photon with the structure of the material. Verification on 11 metals of different crystal structures yields values of in the range 0.84–1.04 Å, corresponding to literature estimates of potential well widths. The paper demonstrates a direct correlation between the type of crystal lattice (FCC, BCC, HCP, orthorhombic), atomic packing density, and the work function: denser packing narrower ionization zone higher work function; sparser packing wider ionization zone lower work function. This demonstrates that: The work function is not an empirical constant – it is derived from geometry The photoelectric effect is evidence of the quantum nature of light, and TVM simultaneously shows that its quantum description is a consequence of the geometric structure of the metal The cutoff wavelength of the electron is geometric – , while the cutoff wavelength of the photon is determined by the effective transformation threshold Keywords: TVM, photoelectric effect, work function, cutoff wavelength, ionization zone, stationarity, crystal lattice, Fermi level, FCC, BCC, HCP, packing density.

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View paper (DOI)Open access versionOpenAlexZenodo (CERN European Organization for Nuclear Research)Published 2026-08-05

Authors: Maričić Zoran