Laval Mayenne Technopole

Epoxidation ofCanola and Sunflower Oils Using Dimethyldioxiranein Microemulsions

Abstract Epoxidized vegetable oils (EVOs) are sustainable, bioderived epoxides potentially useful as green polymer precursors, offering low toxicity, biodegradability, and low environmental impact. This study investigates the epoxidation of canola and sunflower oils using in situ...

UnlockingSimple Hydroboranes for Selective C–HBorylation of (Hetero)arenes

Abstract Control of borane speciation through Me2PhN·BH3 formation enables HBcat-mediated, metal-free C–H borylation of (hetero)arenes via an electrophilic aromatic substitution pathway. The process operates without external catalysts or additives and provides a sustainable platf...