Zhi-Yuan Yang

Trifluoroallyl Sulfonium Salts: Reagents for Highly Regioselective Trifluoroallylation

Abstract We report the design, synthesis, and application of novel bench-stable and scalable trifluoroallylating reagents, trifluoroallyl sulfonium salts (TFASs), which readily react with a series of organozinc reagents under copper catalysis to afford allylic trifluoromethyl-ter...