Yi‐Xia Jia

Palladium-Catalyzed Enantioselective Dearomative Domino Heck/Stille Reaction of Indoles

Abstract Palladium-catalyzed enantioselective dearomative difunctionalization of N-substituted indoles was developed via dearomative carbonpalladation and subsequent capture of benzyl-Pd species by organostannane reagents (domino Heck/Stille reaction). A wide range of 2,3-disubst...

Palladium-Catalyzed Tandem Dearomative Heck Reaction of N -Propiolyl Indoles or Pyrroles with Aryl Bromides

Abstract An efficient Pd-catalyzed tandem dearomative Heck reaction of N-propiolylindoles or pyrroles with aryl bromides has been developed. The protocol provides access to a series of benzopyrrolizinone and pyrrolizinone derivatives bearing a quaternary stereocenter and a tetras...