Renrong Liu

Palladium-Catalyzed Enantioselective Dearomative Domino Heck/Stille Reaction of Indoles

Abstract Palladium-catalyzed enantioselective dearomative difunctionalization of N-substituted indoles was developed via dearomative carbonpalladation and subsequent capture of benzyl-Pd species by organostannane reagents (domino Heck/Stille reaction). A wide range of 2,3-disubst...

Taming the Flexible Eight‐Membered Ring: Enantioselective Synthesis of Inherently Chiral Dibenzo[ a , e ]cyclooctatetraenes Enabled by Pd‐Catalyzed Suzuki–Miyaura Cross‐Coupling

ABSTRACT Inherently chiral molecules generated by the curvature of planar frameworks represent an emerging class of three‐dimensional chiral architectures, yet their catalytic asymmetric synthesis remains highly challenging. Herein, we report a Pd‐catalyzed asymmetric Suzuki–Miya...