Materials & Energyarticle2026-10-10

Frontier orbital control in PIII/PV catalysis

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Abstract

While the familiar Lewis basicity of tricoordinate phosphorus compounds underpins their many uses as ligands, reagents, and catalysts in synthesis, a complementary mode of ‘non-Lewis base’ organoph...

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View paper (DOI)OpenAlexPhosphorus, sulfur, and silicon and the related elementsPublished 2026-10-10

Authors: Alexander T. Radosevich

Institutions: Massachusetts Institute of Technology