Theoretical Study on the Rheology-Driven Lubrication Synergy of Gel on Textured High-Entropy Alloy Coatings

Abstract

This work is a theoretical study aimed to address the lubrication failure of Tom-Pac TP-2557 gel lubricant on the textured high-entropy alloy coatings (THEACs) under wide-temperature-range operating conditions; the rheological lubrication properties of the surface are investigated in this work. Based on lubrication theory and non-Newtonian fluid mechanics, a gel lubrication viscosity model considering temperature dependence and a thermo-mechanical coupled constitutive relationship for the THEACs are established. The results show a significant shear-thinning behavior of the gel within a moderate low-to-medium temperature range, and the onset temperature of thermal degradation is identified. Optimal geometrical and distributional parameters of the surface textures, along with a favorable surface energy range, are determined to achieve desirable interfacial shear strength. Moreover, an anchoring-slip synergistic mode arising from surface energy heterogeneity is found to further enhance lubricating film stability. This research provides a theoretical basis for the gel lubrication design of the THEACs.