Shanghai University of Engineering Science

Deep Cavitand Mediated Selective Aerobic Oxidative Cyclization of Thiols to Cyclic Disulfides

Abstract A mild supramolecular template strategy is reported for the selective synthesis of medium- to macrocyclic disulfides via aerobic oxidative cyclization of α,ω-dithiols in aqueous media. The water-soluble deep cavitand CV-1 serves as a multifunctional platform that synergi...

Unified framework for efficiently computable quantum circuits

Quantum circuits consisting of Clifford and matchgates are two classes of circuits that are known to be efficiently simulatable on a classical computer. We introduce a unified framework that shows in a transparent way the special structure that allows these circuits to be efficie...

MultidimensionalQuantitative Analysis of BiologicalResponses to DNA Nanoassemblies with Defined Structure and SurfaceChemistry

Abstract DNA nanoassemblies (DNs) have emerged as programmable platforms for biomedical applications; however, a quantitative understanding of how structure and surface chemistry jointly govern their biological behavior remains limited. Here, we establish a multidimensional analy...

Technologies for Natural‐Synthetic Polymer Hybrids: Synergistic Biointerface Engineering From Fabrication to Devices

ABSTRACT This review summarizes natural and synthetic polymer hybrid materials for biointerface engineering. Natural polymers like chitosan, collagen, and hyaluronic acid (HA) provide biocompatibility and bioactivity but lack mechanical strength, whereas synthetic polymers such a...

Carbon Dots as ElectrostaticallyDriven Base-SelectiveChemical Compilers for Programmable Nucleic Acid Condensation

Abstract Cells execute complex biological functions through programmed biomolecular condensation, yet a general and programmable strategy for nucleic acid condensation in vitro remains challenging. Here, we demonstrate that carbon dots (CDs) function as an electrostatic-driven ve...

Behavioral Effects and Potential Mechanisms of Imidacloprid-and Flupyradifurone-Induced Neurotoxicity in Caenorhabditis elegans

Abstract Neonicotinoid insecticides raise concerns about neurotoxicity in nontarget organisms, motivating evaluation of alternatives such as flupyradifurone (FPF). We compared the neurotoxicity of imidacloprid (IMI) and FPF in Caenorhabditis elegans after 72 h exposure to 0.1–100...

Cycloaddition EnablesRing Opening of N -Propargyl Oxazolidines:Access to N -Benzyl-2,3-diphenylpyrrolesvia Both C–O and C–C Bond Cleavage

Abstract Aza-diarylmethanes represent a privileged class of pharmacophores found in numerous bioactive molecules. However, conventional synthetic approaches often suffer from the need for prefunctionalized starting materials, harsh reaction conditions, and limited substrate compa...

The lower conductivity of Bi(Ga, Fe)O 3 – x PbTiO 3 ceramics near the morphotropic phase boundary

BiFeO 3 –PbTiO 3 (BF–PT) piezoelectric ceramics have attracted much attention due to the high Curie temperature [Formula: see text] of above 650°C in the vicinity of the morphotropic phase boundary (MPB). The reduction of leakage conduction is essential for practical applications...