Shanghai Academy of Environmental Sciences

VOC observations improve transferable ozone prediction using interpretable machine learning

Abstract Surface ozone variability is controlled by complex interactions among emissions, chemistry, and meteorology, yet the extent to which machine learning models capture chemically meaningful relationships remains uncertain. Here we apply an automated machine learning framewo...

Palladium-CatalyzedAsymmetric Remote Hydroaminationof Internal Alkenes

Abstract Asymmetric catalytic hydroamination of alkenes represents one of the most efficient strategies for constructing chiral N-heterocycles. Herein, we realize the asymmetric intramolecular remote hydroamination of internal cis-alkenes via palladium catalysis. The reaction pro...