Namur Institute of Structured Matter

Boron Monofluoride Complexes Bearing π‐Expanded Coumarin Subunits: Facile Synthesis, Crystal Structure, and Solid‐State Enhanced Emission

Boron-containing compounds have received special interest over the last few years owing to their favorable photophysical characteristics, stimulating their use as fluorescent sensors, in bioimaging and mechanofluorochromic materials. However, their synthesis is often time-consumi...

Resolving Anomalous Cage Escape in Fe(III) Photosensitizers: A Marcus Theory Framework

Abstract The cage escape yield (ΦCE), i.e., the separation of the geminate radical pair formed upon bimolecular excited-state electron transfer, is a key parameter that governs the efficiency of photoredox transformations. For Fe(III) photosensitizers featuring doublet ligand-to-...