Laboratoire de Réactivité de Surface

A comparative study on the immobilization of organic-inorganic polyoxometalates hybrids onto gold electrodes: Direct versus indirect, covalent versus electrostatic grafting

Abstract We explored the conditions of the covalent grafting of organic-inorganic polyoxometalate hybrids onto gold using two basic reactions: the peptide-type coupling between a functionalized POM and a preformed organic self-assembled monolayer and the direct attachment of a th...

Atmospheric Fate of Hydrofluoroethers: Degradation of Parent Compounds and Primary Products by Multiple Oxidants

Abstract Hydrofluoroethers (HFEs) are widely used as substitutes for ozone-depleting substances, yet their atmospheric fate remains poorly understood. We investigated the gas-phase degradation of HFE-7100 (C4F9OCH3) and HFE-7200 (C4F9OC2H5) by OH, Cl, and NO3 at 298 K. The measur...

Multi‐Scale Investigation of Supramolecular Organogels Assembled From Pt(II)‐Salphen Complexes

Supramolecular metallogels based on platinum(II) complexes have attracted growing interest due to their tunable photophysical properties. However, the potential of Pt(II)-salphen complexes as low-molecular-weight gelators remains largely unexplored. Here, we report a series of Pt...