Laboratoire de Chimie des Polymères Organiques

Antibacterial Cyclic Oligo(disulfide)s with Tunable Hydrophilicity Dictate Membrane Interactions and Distinct Metabolic Interference

Abstract To combat drug-resistant bacteria, antimicrobial agents with tunable and multi-modal mechanisms are urgently needed. While membrane-disrupting polymers have been widely explored, precisely regulating their membrane interactions and downstream metabolic effects remains ch...

Polyproline: A Synthetic Polypeptide With Unique Properties

Polyproline is a unique polypeptide defined by its unusual conformational rigidity and physicochemical behavior. Addressing long-standing challenges in its synthesis and characterization, this mini-review highlights recent advances in the ring-opening polymerization of proline N-...

Titanium‐Catalyzed Defluorination of Poly(Vinyl Fluoride) and Poly(Vinylidene Fluoride) Under Friedel–Crafts Conditions

ABSTRACT The defluorination of poly(vinyl fluoride) (PVF) and poly(vinylidene fluoride) (PVDF) fluoropolymers catalyzed by titanium species in the presence of triethylsilane (Et 3 SiH) and aromatic solvents is reported. Commercially available Ti complexes (e.g., [Cp 2 TiCl 2 ] (...

Titanium‐Catalyzed Defluorination of Poly(Vinyl Fluoride) and Poly(Vinylidene Fluoride) Under Friedel–Crafts Conditions

ABSTRACT The defluorination of poly(vinyl fluoride) (PVF) and poly(vinylidene fluoride) (PVDF) fluoropolymers catalyzed by titanium species in the presence of triethylsilane (Et 3 SiH) and aromatic solvents is reported. Commercially available Ti complexes (e.g., [Cp 2 TiCl 2 ] (...

Polymer-Driven Self-Templated Synthesis of Boronate-COF Hollow Spheres: Toward the Development of Size-Selective Nanoreactors

Abstract Covalent organic frameworks are a family of porous crystalline structures gaining attention due to their promising applications. However, despite significant efforts, the synthesis and understanding of uniform and specific morphologies remain a challenge. Herein, we repo...