IMDEA Nanoscience

Signatures of Band-like Charge Carrier Transport in a Three-Dimensional Fe-HHTP Metal–Organic Framework

Abstract Metal–organic frameworks (MOFs) offer exceptional structural and chemical tunability, and the emergence of electrically conductive variants creates new opportunities for functional optoelectronic materials. Here, we investigate charge transport in a three-dimensional (3D...

Polymer Coating Adhesion Drives Functional and Biological Outcomes in Meniscus Implants

Achieving stable integration of drug-releasing polymer coatings with load-bearing meniscus implants remains a challenge in biomaterials engineering. In this study, four surface modification strategies, femtosecond-pulsed laser treatment, oxygen plasma, polydopamine, and an ethyl-...

Inducing Radicality in Gold‐Coordinated Porphyrinoids Through Precise Tip‐Induced Covalent Bond Dissociation

π-Extended porphyrinoids are versatile platforms for the emerging field of π-electron magnetism in conjugated systems. However, achieving controlled bond-selective transformations that enable tuning of their electronic ground states remains a major challenge. Here, we propose a p...

Inducing Radicality in Gold‐Coordinated Porphyrinoids Through Precise Tip‐Induced Covalent Bond Dissociation

ABSTRACT π‐Extended porphyrinoids are versatile platforms for the emerging field of π‐electron magnetism in conjugated systems. However, achieving controlled bond‐selective transformations that enable tuning of their electronic ground states remains a major challenge. Here, we pr...

Tunable Oxygen Connectivity in Carbaporphyrinoid Polymers on Metal Surfaces

ABSTRACT Controlling oxygen‐mediated connectivity at metal surfaces offers a powerful route to engineer covalent and metal–organic architectures with atomic precision. Here, we demonstrate tunable oxygen‐based connectivity in carbaporphyrinoid polymers on Au(111) under ultrahigh...