Guizhou Magic Pharmaceutical (China)

Taming the Flexible Eight‐Membered Ring: Enantioselective Synthesis of Inherently Chiral Dibenzo[ a , e ]cyclooctatetraenes Enabled by Pd‐Catalyzed Suzuki–Miyaura Cross‐Coupling

ABSTRACT Inherently chiral molecules generated by the curvature of planar frameworks represent an emerging class of three‐dimensional chiral architectures, yet their catalytic asymmetric synthesis remains highly challenging. Herein, we report a Pd‐catalyzed asymmetric Suzuki–Miya...