D. Mendeleyev University of Chemical Technology of Russia

Synthesis, Structure and Antibacterial Activity of a Neutral Tin(II) Iodide Complex with 1,2-bis[(4-Methoxyphenyl)imino]acenaphthene

The reaction of tin(II) iodide with 1,2-bis[(4-methoxyphenyl)imino]acenaphthene (4-MeO-BIAN) in anhydrous tetrahydrofuran afforded the neutral complex [(4-MeO-BIAN)SnI(μ-I)]2 (1). A single-phase sample of 1 was isolated and characterized by powder X-ray diffraction and IR spectro...

Four-Year Field Evaluation of a New Thiocyanate Fungicide: Significant Reduction in Late Blight ( Phytophthora infestans ) Severity and Increased Potato Yield

Abstract Late blight, caused by Phytophthora infestans (P. infestans), is a major potato disease worldwide. Resistance of P. infestans to existing fungicides necessitates alternative solutions with other modes of action. Previously, we reported a new family of fungicides: 2-thioc...

Advanced industrial-scale recycling of nickel waste alloys: a driver for circular economy objectives

An eco-friendly electrochemical method of nickel alloy waste leaching was developed for circular economy. The nickel concentration was 72.11 g/L in 100 g/L HCl after 90 A·h, 60 °C and 5 A/dm2 current, while 37.37 g/L nickel was obtained in 100 g/L H₂SO₄ under these conditions. Th...

Ring Contractionof Bicyclic Lactams: A MolecularEditing Aza-Favorski-Type Approach to Tetrahydroquinoline-2-carboxylicAcids

Abstract Development of skeletal editing methods offers new horizons for the acceleration of drug discovery. An original aza-Favorski-type approach is described for the ring contraction of benzazepine-2-ones, providing versatile tetrahydroquinoline-2-carboxylic acids. The sequenc...

N-(4H-1,2,4-triazol-4-yl)imines as Versatile and Readily Accessible Precursors for Nitrile Synthesis

Abstract Herein, we report the selective transformation of N‑(4H‑1,2,4‑triazol‑4‑yl)imines into substituted benzonitriles. These imines are readily accessible from aldehydes. The method provides a rapid and mild procedure that utilizes a previously undescribed nitrogen source. Th...