Zhong‐Quan Liu

Unsaturated Carboxylates as Electrophilic Synthons for Transition‐Metal‐Catalyst‐Free Electroreductive Deoxygenative Coupling

ABSTRACT The use of ester‐derived electrophiles in transition‐metal‐free electroreductive C(sp 3 )─C(sp 3 ) bond formation remains largely unexplored. Herein, we report a sacrificial‐anode‐enabled electroreductive cross‐coupling of simple unsaturated carboxylates with unactivated...

Unsaturated Carboxylates as Electrophilic Synthons for Transition‐Metal‐Catalyst‐Free Electroreductive Deoxygenative Coupling

ABSTRACT The use of ester‐derived electrophiles in transition‐metal‐free electroreductive C(sp 3 )─C(sp 3 ) bond formation remains largely unexplored. Herein, we report a sacrificial‐anode‐enabled electroreductive cross‐coupling of simple unsaturated carboxylates with unactivated...

Cascade Spirocyclization–Difunctionalization or Rearrangement of Bicyclobutyl-Tethered Aldehyde Hydrazones via Strain Release

Abstract A cascade spirocyclization–difunctionalization of bicyclobutyl-tethered aldehyde hydrazones with N-halosuccinimides was smoothly performed to access diverse halo-succinimide-containing diazaspiro[3.3]heptan-3-ones. Meanwhile, the three-component rearrangement of bicyclob...