Zhi-Zhou Pan

From α,β-Unsaturated Amide to Enamide: Intramolecular Alkene Translocation via Iridium-Catalyzed Transfer Hydrogenation

Abstract Site-selective alkene translocation between two separate segments of a molecule has been a rare and mechanistically intriguing transformation. Herein we report the direct conversion of electrophilic α,β-unsaturated amides to nucleophilic enamides via an Ir-catalyzed alke...