Yuanhang Bai

DiastereoselectiveAddition of Racemic α-BorylOrganozinc Reagents to Aldimines

Abstract The addition of alkylzinc reagents to imines is a key route to amines, but suffers from poor selectivity when racemic secondary alkylzincs are employed. Herein, we report a transition-metal-free diastereoselective addition of racemic α-boryl organozincs to aldimines, aff...