Yohan Champouret

Stereoselective trans -1,4 Polymerization of Isoprene and β -Myrcene Mediated by Iron Complexes Bearing 1,1-Diaryl- N -(quinolin-8-yl)methanimine Ligands

Abstract Although iron has emerged as an earth-abundant alternative for 1,3-diene coordinative polymerization, stereoselective iron systems remain uncommon and are often associated with limited catalytic activity. Here, we report three iron(II) complexes supported by 1,1-diaryl-N...

Coordinative chain transfer homopolymerization and copolymerization of bio‐sourced β ‐myrcene and butadiene promoted by iminopyridine iron complexes

Abstract A family of iron complexes bearing iminopyridine (ImPy) ligands with systematic variations on the N ‐aryl and pyridine moieties was evaluated as pre‐catalysts for the coordinative polymerization of β‐myrcene and butadiene. Upon activation with Al i Bu 3 and trityl borate...