Yanqiu Zhu

Tailoring the d‐Band Center via Multi‐Metal–Phosphorus d–p Orbital Hybridization in a High‐Entropy Metal Phosphide to Enable Accelerated Sulfur Redox Kinetics

ABSTRACT Sluggish lithium polysulfide (LiPS) reduction kinetics and the shuttle effect lead to low active mass utilization and poor cycling stability, thereby seriously hampering the commercial application of Li–S batteries. Herein, a theoretically guided high‐entropy phosphide (...