Yan‐Qiong Sun

A Bismuth-Incorporated Telluroniobate with a Crown-Like {Bi3Te3} Heterometal-Oxo Ring: Structure and Photocatalytic Aerobic Ipso-Hydroxylation of Organoboronic Acids

Abstract A novel inorganic–organic hybrid bismuth-incorporated telluroniobate, H[Cu(H2O)(en)2]6[BiIII3(H2O)6TeIV5Nb18O66]·24H2O (1, en = ethylenediamine), is built from a unique peanut-shaped sandwich-type {BiIII3(H2O)6TeIV5Nb18O66} ({Bi3Te5Nb18}) polyanion and [Cu(en)2(H2O)]2+ c...