Won Jun Jang

Nickel-Catalyzed Reductive Alkylation of Aldimines with Unactivated Alkyl Iodides

Abstract A nickel-catalyzed reductive alkylation of directing-group-free N-sulfonyl and N-aryl aldimines is reported. The reaction proceeds at ambient temperature and accommodates unactivated primary, secondary, and tertiary alkyl iodides as well as selected activated alkyl bromi...