V. Subramanian

Ligand Accelerated Palladium-Catalyzed C–H Arylation of Electron-Deficient Polyfluoroarenes with Aryl Bromides

Abstract A ligand accelerated highly efficient palladium-catalyzed C–H arylation of electron-deficient polyfluoroarenes with aryl and heteroaryl bromides has been developed. The reaction proceeds efficiently under mild conditions with low catalyst loading (0.25 mol % Pd) and liga...

Flat-Band-Assisted Nitrogen Reduction on M-N4 Single-Atom Catalysts in a Two-Dimensional Tetraaza[8]circulene Framework

Abstract The porphyrin-like M-N4 coordination environment embedded in two-dimensional (2D) lattices represents a compelling design principle for single-atom electrocatalysts (SACs) targeting the electrochemical nitrogen reduction reaction (eNRR). Density functional theory (DFT) c...