Troels Skrydstrup

Tuning Second-Sphere Amine Basicity to Modulate Hydride Intermediates and Selectivity in Molecular Manganese Bipyridine CO2 Electroreduction

Abstract Manganese bipyridine tricarbonyl complexes represent a prominent class of molecular electrocatalysts for efficient and selective CO2-to-CO conversion. Recent efforts have sought to redirect product selectivity toward HCOOH by incorporating second-sphere amine proton rela...

Design of Experiments for Diverse Carbon Isotope Labeling with Aryl Thianthrenium Salts

Abstract A method for accessing structurally diverse carbon-isotope-labeled products from aryl thianthrenium salts has been established. The use of near-stoichiometric amounts of ex situ-generated carbon monoxide along with simple, air-stable palladium catalysts allows for the sy...