Toshifumi Satoh

Fluorine-Modulated Reactivity Enables One-Pot Kinetic Sequence Programming of Block Copolyesters

Monomer sequence strongly influences copolymer properties, but direct block formation from a monomer mixture requires a large reactivity contrast. Here, fluorination was used to regulate anhydride reactivity in the cesium pivalate-catalyzed ring-opening alternating copolymerizati...