Author
Toma Osawa
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Recent research
- Health & Medicine
Oxidative Fluorination of β-Ketoamides: Guanidinium Iodides as Iodoarene Alternatives
Abstract A guanidinium iodide-catalyzed oxidative fluorination of β-ketoamides enables umpolung α-fluorination, replacing iodoarenes with a simple iodide source. Using HF·pyridine as the fluoride source and mCPBA as the oxidant in dichloroethane, quaternary α-fluoro-β-ketoamides...