Tom Willhammar

Phenol-Driven Modulation Enables the Crystallization of Titanium Metal–Organic Frameworks

Abstract Titanium-based metal–organic frameworks (MOFs) remain among the most challenging frameworks to synthesize due to the high reactivity of Ti(IV) precursors, particularly when in combination with strongly coordinating phenolate ligands. Phenol is an untapped modulator for M...

Diamondiyne: A 3D Carbon Allotrope With Mixed sp–sp 3 Hybridization

ABSTRACT The creation of carbon allotropes is synthetically highly challenging, but their practical significance to science and technology cannot be underestimated. Here, we report the synthesis of a new carbon allotrope, diamondiyne, which is the second known one (after diamond)...