Tom S. Bennett

Probing the Conformational Behavior of a Seven Hetero-Spin Supramolecule

Abstract The synthesis and crystal structure of a 7-spin supramolecular poly-rotaxane is reported. The [4]rotaxane structure involves a trigonal thread centred on a {CrNi2} core, with each of the three arms terminated by Cu(II) centres and bearing a {Cr7Ni} metallocycle. The macr...