Tianqi Xia

Bulky Borylphosphido Complexes of Iron and Cobalt with N-Heterocyclic Carbene as an Ancillary Ligand

Abstract Terminal primary phosphido metal complexes are valuable synthetic reagents and intermediates for phosphination reactions and phosphinidene species. Their tendency to aggregate to form bridging phosphido complexes, however, poses a synthetic challenge. Herein, we show tha...