Tharmalingam Punniyamurthy

Rh-Catalyzed Cascade C–H Functionalization/Annulation of Ketimine Directed Arenes with Vinylcyclopropanes: Access to Bridged Azaheterocycles

Abstract Rh-catalyzed cascade C–H functionalization/annulation of ketimine-directed arenes with vinylcyclopropanes has been accomplished to access N-bridged cyclic frameworks. The procedure can be extended to vinylaziridine, vinyloxirane, and vinyl ethylene carbonate to furnish s...

Rh‐Catalyzed C─H Functionalization/Annulation/Skeletal Editing of Arylamides With Sulfoxonium Ylides: Access to Dihydroisoquinolinones and Benzodiazepinones

Rh(III)‐catalyzed redox‐neutral cascade C─H functionalization and annulation of arylamides with sulfoxonium ylides has been accomplished to produce 3,4‐dihydroisoquinolinones, which can be skeletal edited to furnish diazepinone structual frameworks. Substrate scope, functional gr...