Takuya Yamamoto

Luminescence Control in Polyesters via Chain‐Motion‐Regulated Through‐Space Electronic Interaction

ABSTRACT Stimuli‐responsive luminescent polymers translate changes in molecular mobility or transformation into optical outputs; however, most systems rely on synthetically elaborate architectures that hinder broad implementation. Here, a very simple polyester, synthesized via ri...

Fluorine-Modulated Reactivity Enables One-Pot Kinetic Sequence Programming of Block Copolyesters

Monomer sequence strongly influences copolymer properties, but direct block formation from a monomer mixture requires a large reactivity contrast. Here, fluorination was used to regulate anhydride reactivity in the cesium pivalate-catalyzed ring-opening alternating copolymerizati...