Sun-Gil Park

A Modular and Divergent Strategy for Dibenzo[ b,f ]oxepine Natural Products: Total Syntheses of Pacharin, Bauhiniastatins 1–4, and Bauhinoxepins C–J and Structural Revision of Bauhinoxepin F

Abstract We report the development of synthetic routes to representative Bauhinia family natural products, including pacharin, bauhiniastatins 1–4, and bauhinoxepins C–J. The key transformation involves a one-pot aldol condensation/SNAr sequence to efficiently construct the diben...