Stephen P. DiLuzio

Homogeneous Iron Porphyrin as a Molecular CO Shuttle Enables Electrochemical Multicarbon Product Formation from CO2

Abstract Homogeneous molecular catalysts for electrochemical CO2 reduction are generally limited to two-electron-reduced C1 products, primarily CO. Here we propose and demonstrate a fundamentally distinct role for molecular catalysts: as reversible CO shuttles that enhance the lo...