Sankash Mitra

Catalytic Asymmetric Allylic Substitution with Alkynylogous Silyl Enol Ethers En Route to Chiral Allenes

Abstract Despite their potential as building blocks of allenes, alkynylogous enol silanes have rarely been employed in organic synthesis. Herein, we establish their utility as nucleophiles in catalytic asymmetric allylic substitution, which results in skipped enallenes bearing tw...