Sankar Prasad Rath

Hydrogen Bonds Regulate Paramagnetic Spin Delocalization in Ferric Hemes

Abstract Hydrogen bonds in metalloprotein active sites regulate reactivity and facilitate electronic communication between metal centers and their surrounding environment. However, systematic control over hydrogen-bond-mediated spin delocalization has not been achieved in a synth...

Cover Feature: Electronic Coupling in Cofacial Heterobimetallic AgCu‐Porphyrin Dimers: Bioinspired Analogs of Chlorophyll Special Pairs

Nature's photosynthetic special pair demonstrates how precise molecular organization channels light energy into directed electronic communication. The Cover Feature reimagines this principle through cofacial AgCu–porphyrin dimers, revealing how subtle, bridge-controlled structura...