Sabyashachi Mishra

Spin-Vibronic Mechanism of Light-Driven Coordination-Induced Spin-State Switching in a Nickel(II) Complex

Abstract In Ni(II) complexes, spin-state switching is governed by changes in the coordination number and the nature of the ligand field. We report the ultrafast photorelaxation of an axial-pyridine-coordinated octahedral Ni(II) complex with a phenazine fluorophore using multi-con...

ControllingSpin-Vibrational Coupling and Spin Relaxationin Cu(II) Molecular Spin Qubits via Ligand Rigidity

Abstract A clear understanding of spin relaxation is central to the design and development of molecular spin qubits. A detailed computational study of spin-vibrational coupling and spin–lattice relaxation is presented here for a series of Cu(II) complexes with varying ligand rigi...