Rodrigo A. R. Carvalho

Oxygen-Vacancy-Controlled Band-Gap Engineering in Fe/Co Co-doped La-Modified Bismuth Titanate: Integrated Experimental and First-Principles Analysis

Abstract Layered Aurivillius ferroelectrics offer a route to multifunctional band-gap engineering, yet the role of oxygen vacancies in band-edge reconstruction in Fe/Co-modified compositions remains poorly resolved. Here, oxygen annealing of Bi3.25La0.75Ti2.60(Fe0.50,Co0.50)0.40O...