Rodney J. Blanchard

Disentangling Modulator and Fluoride Chemistry in Rare-Earth Metal–Organic Framework Formation via Multinuclear NMR Spectroscopy: A Mechanism-Guided Synthetic Redesign

Abstract Metal–organic framework (MOF) chemistry continues to expand, highlighting the need for molecular insight into framework formation. Solution-phase NMR provides a powerful, accessible, and economical means to probe these mechanisms. We examine the formation of rare-earth (...