Rainer Pöttgen

Borosulfates Hosting Se 4 2+ Ions—Crystal Structures, Chemical Bonding, Optical Spectroscopy, and Magnetism

ABSTRACT Despite consistent growth in the number of compounds known to host homo‐ and hetero polycations of group 16 elements, only two, Se 4 [HS 2 O 7 ] 2 and Se 4 [S 4 O 13 ], provided an exclusively oxidic coordination environment, the former being the first structural charact...

Up and Downthe Hill-Plot: Hydrides of CeGe–Structureand Magnetism

Abstract The hydrogenation behavior of FeB type CeGe was investigated. Hydrogenation (deuteration) produces mixtures of two modifications, similar to hydrides of other FeB type phases LnTt (Ln = La, Ce, Nd; Tt = Si, Ge). P-CeGeD0.75(2) (Pnma, a = 8.1603(5) Å, b = 4.0938(3) Å, c =...