Raghunathan Ramakrishnan

A Chemical Space Perspective on Diastereomeric Barriers in Alkylperoxy-to-Hydroperoxyalkyl Isomerization

Abstract Low-temperature hydrocarbon autoxidation involves radical intermediates whose reactivity depends not only on the stereochemistry of the intermediates themselves, but also on that of the transient species encountered along the reaction path. This study offers large-scale...