Qin Luo

Brønsted Acid-Catalyzed Nitroso-Diels–Alder Reaction of 2-Trifluoroacetamido-1,3-dienes

Abstract The nitroso-Diels–Alder (NDA) reaction represents a powerful strategy for the assembly of 3,6-dihydro-1,2-oxazines for nearly a century, owing to its efficiency and broad utility in synthesizing natural products and bioactive molecules. Despite these advancements, tradit...

Fe(III)-MediatedOxidative [5 + 1] Cyclization forthe Highly Site-Selective Synthesis of Functionalized Quinoline Derivatives

Abstract We describe a method for the construction of highly functionalized quinoline derivatives from enaminones via an oxidative [5 + 1] cyclization. A plausible mechanism may involve a cascade sequence including single-electron transfer (SET), radical Michael addition, elimina...