Qiang Xiao

Electrochemical Oxidative Dearomatization of Indole with Carboxylic Acid via 1,2-Acyloxy Migration for the Synthesis of C2-Quaternary Indolin-3-ones

Abstract Herein, we develop an efficient KBr-promoted electrochemical strategy that enables the oxidative dearomatization of indoles with carboxylic acids via 1,2-acyloxy migration, establishing a mechanistically different method to synthesize structurally diverse C2-quaternary i...

Electrochemical Nickel-Catalyzed Cross-Electrophile Coupling: A Sustainable Platform for C(sp3)–C(sp3)/C(sp2) Bond Construction

Abstract An electrochemical nickel-catalyzed cross-electrophile coupling reaction of organic halides with cyclosulfonium salts to construct C(sp3)–C(sp3)/C(sp2) bonds is reported. This highly selective synthetic approach demonstrates significant practical utility, as evidenced by...