P.S. Jaget

DFT supported experimental evaluation of air oxidation converting a thiosemicarbazone oxidovanadium(IV) to a dioxidovanadium(V) complex

Two novel vanadium complexes, viz., an oxidovanadium(IV) complex [VO(HL)(acac)] (1) and a dioxidovanadium(V) complex [VO₂(HL)(H₂O)] (2), were synthesized using the tridentate ONS-donor Schiff base ligand H₂L (N-(dehydroacetic acid)-4-phenyl-3-thiosemicarbazone). The complexes wer...