Phillip Christopher

Interfacial Electrolyte Solution Reorganization as a Rate-Limiting Step for CO Adsorption on Pt in Electrochemical Environments

Abstract Electrolyte solutions play a central role in determining the thermodynamics and kinetics of electrochemical reactions. Recent experimental and theoretical studies have proposed that reorganization of interfacial solvent structures can be correlated with electrocatalytic...

Mn Disproportionation, Not Redox Cycling, Explains Low-Temperature, Thermochemical “Water Splitting” with MnFe2O4/Na2CO3

Abstract The development of redox-active materials for thermochemical water splitting to produce hydrogen is an attractive alternative to water electrolysis due to the low cost of heat and generally favorable scaling relationships of heat-driven processes. Recently, a material sy...