Peter Robatscher

Solvent-Cage-Controlled Radical Flux and Reactive Adduct Intermediates Govern Azo-Initiated Oxidation

Abstract Radical-mediated oxidation underlies processes ranging from oxidative stress in biological systems to antioxidant evaluation in food and pharmaceutical chemistry. In widely used azo-initiated systems such as those based on 2,2′-azobis (2-amidinopropane) (AAPH), radical f...