Patrick M. Woodward

Metal–Metal Interactions in Hexagonal Perovskites Containing Bimetallic Face-Sharing Bioctahedra

Abstract Recent studies have revealed metal-to-metal and intervalence-charge transfer transitions in cation ordered 6H perovskites with Cs3M+M2+M3+Cl9 stoichiometry. The structure and properties of two new members of this family, Cs3NaMnVCl9 and Cs3NaMnCrCl9, are reported here. I...