Pablo J. Sanz Miguel

Diastereoselective Axial-to-Chelate-Puckering Chirality Transfer in cis -[PtCl2(DABN)] Complexes

Abstract Axially chiral 1,1′-binaphthalene-2,2′-diamine (DABN) was used to control chelate-ring puckering in cis-[PtCl2(DABN)] complexes. Coordination of Ra- or Sa-DABN affords the enantiomeric complexes cis-λ-[PtCl2(Ra-DABN)] (λ,Ra-1) and cis-δ-[PtCl2(Sa-DABN)] (δ,Sa-1), respect...