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Enantioselective Defluorinative C(sp2)–H Allylation of Acrylamides Enabled by CpxRh(III) Catalysis

Abstract Chiral fluoroalkenes are high-value synthetic targets; however, the development of efficient catalytic asymmetric methods for their assembly from abundant precursors remains a formidable challenge. Herein, we report a convergent strategy that merges asymmetric alkenyl C(...