Michael Morasch

Double Reduction of Ph 3 B to a Dianionic Borane With a Powerful Sr I Intermediate

ABSTRACT Reduction of [(BDI)SrI] 2 with KC 8 generated in situ a (BDI)Sr I species which enabled the reduction of Ph 3 B to the Ph 3 B 2− dianion (BDI = HC[(Me)C═N‐DIPeP] 2 , DIPeP = 2,6‐(Et 2 CH) 2 ‐phenyl). The product (BDI)Sr(BPh 3 )Sr(BDI) features a Ph 3 B 2− dianion that is...